CORRELATED SUBSYSTEMS IN SUPERIONIC CONDUCTORS AND SEMICONDUCTORS
Main researcher
: VUČIĆ, ZLATKO (53532) Assistants
TONEJC, ANĐELKA (50121)
AVIANI, IVICA (76256)
OGORELEC, ZVONKO (33971)
TONEJC, ANTUN (50132)
MILAT, OGNJEN (77950)
GLADIĆ, JADRANKO (86441)
DŽUBUR, ADIL (94100)
Type of research: basic Duration from: 01/01/91. to 12/31/95. Papers on project (total): 47
Papers on project quoted in Current Contents: 17
Institution name: Institut za fiziku, Zagreb (35) Department/Institute: Semiconductor physics department Address: Bijenička cesta 46, P. p. 304 City: 10000 - Zagreb, Croatia
Communication
Phone: 385 (0)1 271 211
Fax: 385 (0)1 421 156
E-mail: vucic@olimp.irb.hr
Summary: The growth of two-component superionic conductors single
crystals (nonstoichiometric cuprous selenide Cu2-xSe) under the
thermodynamical equilibrium conditions and their characterization were the
subject of research work. Preliminary the equilibrium shape single
crystals up to 5 mm in diameter were obtained. The crystal facetting was
monitored and the size measurements performed during the growth. The
temperature dependent structural changes of quasi-1D CDW system of the new
generation ((NbSe4)10I3) were investigated, in order to find structural
background for the anomalous behaviour of its transport and thermal
properties. The most prominent and reversible structural effect found
below Peierls transition is symmetrically equivalent monoclinic splitting
of tetragonal lattice. Basically related to a shearing mode along chains,
it appears to be a direct consequence of interchain CDW interaction. The
correlated subsystems in complex crystal structures were investigated by
electron microscopy and electron diffraction on several types of
high-temperature superconductors (metal doped copper oxides): Ca.85CuO2,
(Sr/Ca).85CuO1.71, MSr2(RE)nCu2O5+2n; M=Ga,Co,Al or C,S,...; n=0,1,2,3.
All cuprates investigated revealed two interpenetrated lattices-subsystems
with various partial structures - chains, bands, loops, nets. Interactions
within each subsystem result in formation of the particular sublattice of
a different translation symmetry in common crystal structure. The mutual
interactions of different subsystems produce either an incommensurate
modulation of common crystal structure or a commensurate superstructure.
Keywords: equilibrium crystal shape, surface roughening, superionic conductors, mobile ion subsystem, short range order, quasi-onedimensional conductors, haloids of metal-tetrachalcogenoids, incommensurate-commensurate phase transition, cuprates, high-Tc superconductors, layer compounds, superstructures, substructures, modulated structures, electron microscopy and diffraction
Research goals: The investigation of superionic conductors is
primarily aimed at better understanding of the type and range of ion-ion
interaction within the mobile-ion subsystem, as well as of interactions
between the two coexistent subsystems - mobile ions and the immobile cage
lattice. The growth and morphological study of equilibrium shape single
crystals is focussed on temperature and concentration dependence of facet
types and size and critical behaviour of the shape of curved surface near
a facet edge, reflecting the interactions in a crystal. The research on
superconducting ceramics - cuprates should provide better understanding of
the correlation between the superconductivity phenomena and the layered
crystal structure, i. e. the number of Cu-O planes and the ordering in
these planes.
COOPERATION - PROJECTS
Name of project
: B/CI1*-913183 Investigation of structural
properties and phase transitions in anisotropic systems with
incommensurately modulated structures Name of institution: Rijksuniversiteit Groningen
Inorganic Laboratory
Department of Chemistry Nyenborgh 16 City: 9747 AG - Groningen, Netherlands
Name of project
: B/CI1*-913167 Structural properties of
superionic conductors Name of institution: EMAT University of Antwerp (RUCA)
Groenenborgerlaan 171 City: B-2020 - Antwerpen, Belgium
Name of project
: SU*03*017 National impulse programme on high-Tc
superconductivity Name of institution: EMAT University of Antwerp (RUCA)
Groenenborgerlaan 171 City: B-2020 - Antwerpen, Belgium
Name of project
: IUAP*11 Incentive program on high-Tc
superconductors Name of institution: EMAT University of Antwerp (RUCA)
Groenenborgerlaan 171 City: B-2020 - Antwerpen, Belgium Other information about the project.