SVIBOR - Project code: 1-07-193

MINISTRY OF SCIENCE AND TECHNOLOGY

Strossmayerov trg 4, HR - 10000 ZAGREB
tel.: +385 1 459 44 44, fax: +385 1 459 44 69
E-mail: ured@znanost.hr

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Project code: 1-07-193


STRUCTURE AND REACTIVITY OF ORGANIC COMPOUNDS


Main researcher: MAKSIĆ, MIRJANA (27544)


Assistants
Type of research: basic
Duration from: 01/01/91. to 12/31/93.
Papers on project (total): 92
Papers on project quoted in Current Contents: 39
Institution name: Institut "Ruđer Bošković", Zagreb (98)
Department/Institute: Department of Organic Chemistry and Biochemistry
Address: Bijenička c. 54
City: 10000 - Zagreb, Croatia
Communication
Fax: 385 (01) 425 647
Phone: 385 (01) 425 649
E-mail: MMAKSIC EMMA.IRB.HR
Summary: Investigations within the project encompass: (a) Synthesis, spectroscopic and theoretical studies of 7-oxanorbornenes connected via sigma, pi or aromatic bridges with emphasis on studying nature of long-range intramolecular interactions between lone pairs and their influence on the extent of pi,pi-interactions within considered molecules; (2) Synthesis, spectroscopic and theoretical studies of strained organic and organometallic compounds; (3) Thermochemistry of novel organometallic derivatives of cyclopropene; (4) development of ionic hydrogenation systems of interest for coal chemistry.

Keywords: intramolecular interactions,polycyclic ethers,strained compounds,superacids

Research goals: The results are expected (1) to contribute to the understanding of the mechanism of intramolecular orbital interactions of interest for understanding electron transfer processes in fused 7-oxanorbornenes and their saturated and/or substituted analogues ; (2) to provide a firm experimental basis for understanding the influence of 14b metals on the electronic structure and reactivity of strained hydrocarbons; (3) to contribute to the development of new building blocks and reagents for their "glueing" into macropolycyclic systems of practical interest as well as to the development of specific, highly selective reaction procedures (as ionic hydrogenation), thus leading eventually to new useful materials; (4) to shed light on the reactivity and biochemical activity of vitamin C derivatives.

COOPERATION - PROJECTS


  1. Name of project: Aufklaerung von Mechanismus und Stereochemie der Verknuepfung von 7-Oxanorbornenen (putem programa suradnje s KFA Juelich)
    Name of institution: Organisch-chemisches Institut der Universitaet Essen
    City: Essen, Njemačka

COOPERATION - INSTITUTIONS


  1. Name of institution: Institut fuer Organische Chemie, Karl-Franzens Universitaet
    Type of institution: University/Faculty
    Type of cooperation: Joint publishing of scientific papers
    City: Graz, Austrija

  2. Name of institution: Institut fuer Organische Chemie, Universitaet Essen-GH, FRG
    Type of institution: University/Faculty
    Type of cooperation: Joint publishing of scientific papers
    City: Essen, Njemačka

  3. Name of institution: Institut fuer Organische Chemie Universitaet Heidelberg, (u okviru suradnje Baden Wurttemberg)
    Type of institution: University/Faculty
    Type of cooperation: Joint publishing of scientific papers
    City: Heidelberg, Njemačka

  4. Name of institution: Institut fuer Organische Chemie, Muenster, FRG (putem programa suradnje s KFA Juelich)
    Type of institution: University/Faculty
    Type of cooperation: Joint publishing of scientific papers
    City: Muenster, Njemačka

  5. Name of institution: College of Arts and Sciences, The University of Tokyo
    Type of institution: University/Faculty
    Type of cooperation: Systematic exchange of information
    City: Tokyo, Japan

  6. Name of institution: Odjel za kemiju i kemijsku tehnologiju, Sveučilište u Ljubljani
    Type of institution: University/Faculty
    Type of cooperation: Systematic exchange of information
    City: Ljubljana, Slovenija

  7. Name of institution: Structural Chemistry Research Group, Eoetvos University Budapest
    Type of institution: University/Faculty
    Type of cooperation: Occasional exchange of experts
    City: Budapest, Mađarska

  8. Name of institution: Department of Chemistry, University of Minnesota
    Type of institution: University/Faculty
    Type of cooperation: Joint publishing of scientific papers
    City: Minneapolis, SAD
Other information about the project.
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Last update: 10/10/95
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