A Study of Solid Metastable Phase Formation in Precipitation Processes from Solution
Main researcher
: BREČEVIĆ, LJERKA (5334) Assistants
KRALJ, DAMIR (120470)
LUGARIĆ, JASMINKA (189921)
Type of research: basic Duration from: 06/01/92. to 12/31/95. Papers on project (total): 19
Papers on project quoted in Current Contents: 5
Institution name: Institut "Ruđer Bošković", Zagreb (98) Department/Institute: Department of Chemistry Division for Technology, Nuclear Energy and Protection Laboratory for Precipitation Processes Address: Bijenička cesta 54, 10001 Zagreb, p.p. 1016 City: 10000 - Zagreb, Croatia
Communication
Phone: 385 (0)1 4561-004
E-mail: brecevic@olimp.irb.hr
Fax: 385 (0)1 425-497
Summary: In the proposed project the study was directed toward
gaining fundamental knowledge about the factors influencing
thermodynamically metastable and stable phase formation in precipitation
processes. An expertise arising from a physical chemical approach was used
with a view to collect data about changes in the solid and liquid phases
during these processes. Specific objectives were: (i) to define conditions
under which the formation of metastable and stable phases is possible and
can be studied; (ii) to investigate kinetics and mechanisms of nucleation,
growth, dissolution and phase transformation of these solid phases using
different experimental techniques; (iii) to study the interactions between
solid phase and solution, the solid phase modifications and foreign ions
and/or molecules, as well as the properties of the solid phase(s) formed
and the foreign molecules added; (iv) to introduce the liquid membrane
technique into the investigation of precipitate properties and the
selective separation of sparingly soluble salts of similar properties from
a suspension. Initial work was done using calcium carbonate as a model
system since it is known that this forms several anhydrous polymorphs and
hydrated forms, all of them except calcite being metastable. The study was
also extended to some other inorganic (oxalates, silica) and organic
(hydrocarbons) model systems. The objective of the study was to develop
generic solutions to a wide range of problems that involve precipitation
processes, as well as interactions between the solid phase and foreign ions
and molecules, such processes being common in many sectors of industry, in
biological and medical processes and in natural phenomena.
Research goals: The aim of the proposed study was to investigate
metastable and stable solid phase formation and their behaviour in
precipitation processes using the expertise arising from a physical
chemistry background. Specific objectives were: (i) to determine the
equilibria conditions in solid/liquid systems; (ii) to investigate
formation, growth, dissolution, and transformation kinetics and mechanisms
of different metastable and stable phases using different experimental
techniques; (iii) to develop mathematical models of the interactions
between these processes; (iv) to define thermodynamic and kinetic
parameters of precipitation processes at equilibrium and dynamic
conditions; (v) to characterize some metastable forms; (vi) to study the
influence of additives and efficiency of their action on the precipitates
and processes involved; (vii) to introduce the liquid membrane (LM)
technique and apply it in the study of heterogeneous systems. Calcium
carbonate was used as a first model system and some other inorganic
(oxalates, silica) and organic (alkanes) systems were also investigated.
By introducing the LM technique, a selective dissolution and separation of
sparingly soluble salts of similar properties were investigated. Results
define conditions at which a certain solid phase(s) forms and is stable as
well as properties of the solid phase. Kinetics and mechanisms of the
examined processes and the interactions between solid phase and additives
are also given.
COOPERATION - PROJECTS
COOPERATION - INSTITUTIONS
Name of institution
: Tehnološki fakultet Sveučilišta u Splitu Type of institution: University/Faculty Type of cooperation: Joint publishing of scientific papers City: 21000 - Split, Croatia
OTHER ACHIEVEMENTS
Name
: Nagrada Hrvatskog kemijskog društva za koloidnu i
površinsku kemiju u 1994. godini Type of achievement: Other Authors: Dobitnik dr. Damir Kralj Other information about the project.