Type of research: applied Duration from: 01/01/91. to 12/31/94. Papers on project (total): 33
Papers on project quoted in Current Contents: 4
Institution name: Fakultet kemijskog inženjerstva i tehnologije, Zagreb (125) Department/Institute: Department of inorganic chemical technology and non-metals Address: Marulićev trg 20 City: 10000 - Zagreb, Croatia
Communication
Phone: 385 (0)1 4552-477
Fax: 385 (0)1 4550-725
Summary: Processes of nucleation and crystallization in the course
of accquiring transparent glass-ceramics with mullite, Zn-spinel and
high-quartz solid solution have been studied. Mechanism of
crystallization of high-quartz solid solution, mullite, Zn-spinel, and
influence of dopants (Co, Mn, Fe ) on kinetic parameters in non-isothermal
conditions were investigated. With the mathematical modeling and computer
simulation new methods were established, for studying the processes of
nucleation and crystallization of two or more phases, that occur in the
same temperature range. A special mathematical model was derived to
separate the processes of nucleation and crystal growth of each phase, and
thus to influence the microstructure and properties of glass-ceramics.The
sol-gel method has been used to prepare single-phase and diphasic
aluminosilicate gels. The influence of preparation routes on the phase
development and sintering behaviour of mullite powders (with nanometer
particles size) needed for the production of high density mullite ceramics
has been studied.
Research goals: To obtain ceramic materials by controlled
crystallization of glasses or by synthering of amorphous powders (obtained
by sol-gel technics) it is particularly important to control theprocesses
of nucleation and crystallization and to establish the influence of
various factors as: nucleating agents,dopants,thermal treatment and the
composition of glasses on the phase composition and microstructure of
ceramic products.The aim of this research is to find out how each of the
mentioned factors influences the process of nucleation and
crystallization, in order to prepare materials with strictly defined
properties.Results of the investigation will increase the theoretical and
practical knowledge in the field of controled crystallization of glases
and sintering of aluminosilicate gels,that are neceseary to produce
glass-ceramics and ceramicsmaterials at lower temperatures than
nowdays.Because of an increasing need for the materials with fully new
combination of properties in electronic, telecomunications, rocket
technics and machine building,the correlation of structure and properties
becomes of an extreamly fundamental and practical significance.
COOPERATION - INSTITUTIONS
Name of institution
: Institut fuer Neue Materialien, Universitat
des Saarlandes ( suradnja uspostavljena 1993. godine) Type of institution: Economical/Production Type of cooperation: Joint publishing of scientific papers City: D-66123 - Saarbruecken, SR Njemačka Other information about the project.