Type of research: basic Duration from: 01/01/91. to 12/31/95. Papers on project (total): 94
Papers on project quoted in Current Contents: 37
Institution name: Institut "Ruđer Bošković", Zagreb (98) Department/Institute: Center for Marine Research - Zagreb, Laboratory for Ecological Modelling Address: P.P. 1016, Bijenička 54, Zagreb, Croatia. City: 10000 - Zagreb, Croatia
Communication
Phone: 385 (0)1 461 111
Fax: 385 (0)1 425 497
E-mail: legovic@olimp.irb.hr
Summary: Eutrophication is a state of estuarine ecosystem under
increased inflow of nutrients. Investigated are fundamental physical,
chemical and biological processes in the stratified estuary and coastal sea
and their effect on eutrophication. By application of existing and
development of new methods, organic films are characterized and their role
in eutrophication and accumulation of pollutants is investigated. Of
particular importance is the accumulation of organic particles and
pollutants at density interfaces (halocline), formation of organic films
and their rola in the eutrophication phenomena, and fate of pollutants.
Organic thin films are characterized at natural interfaces (halocline) and
model interfaces (electrode/solution). Transformations of dissolved organic
matter and particles, including the unicellular organisms, are studied at
model interfaces. Organic and organometalic thin films of high charge
density are investigated as new materials for sensors.
Models are developed for reconstruction and prediction of consequences in
the estuary and neighbouring coastal sea of man induced changes in nutrient
and pollutant inflow.
Research goals: GOALS: By applying the existing and by developing
new methods of characterization of biogeochemical processes and organic
structures at the salinity gradient (halocline) and by formulation of new
models of transport of substances and biological interactions, following
will be examined: 1) organic films which are formed by transformation of
allochtonous surface active particles and phytoplankton exudates which
includes: condensation, heterocoalescence and spreading; 2) transport
processes of particles, dissolved matter (inluding oxygen) and heat through
the halocline as well as growth and transport of (fresh and marine)
phytoplankton; 3) possibility to predict biological and chemical
consequences of antropogenic and natural nutrient and pollutant inflows in
estuaries and associated coastal seas. EXPECTED RESULTS: Understanding of:
a) formation of organic films on the salinity gradient; b) impact of
material input on formation and decomposition of the films; c) impact of
atmospheric perturbations and sea currents on the film stability; d)
hydrophobic pollutant accumulation on the film; e) heat transport and its
effect on primary production and degradation rates; f) oxygen transport;
h) dynamics of phytoplankton. New methods: a) Electrochemical counter of
surface active particles; b) method for characterization of individual
surface active particles and phytoplankton cells; c) method for preparation
and characterization of organic and organometallic films; d) molecular
detectors for characterization of adatoms; e) method for calculating
exchange of water masses and particles in estuaries; f) model of particle
transport in 2-dimensions; g) method for calculating total balance of
nutrients and pollutants in estuaries and coastal seas; h) ecological model
of the dynamics of phytoplankton and oxygen in a stratified estuary and
coastal seas. NEW MATERIALS: a) stable 2-dimensional compounds of
heteroaromatic molecules with sulphur; b) organometalic films with high
electron density.
COOPERATION - PROJECTS
Name of project
: Transport i disperzija tvari u polju slučajnih
brzina Name of institution: Matematika, Prirodoslovno-matematički fakultet,
Sveučilište u Zagrebu City: 10000 - Zagreb, Croatia
Name of project
: Development de methodes electroanalitique et
d'instrumentation correspondante pour la recherce d'environment aqueux Name of institution: Laboratoire d'Electrochimie, Universite Pierre
et Marie Curie City: 75230 - Pariz, Francuska
Name of project
: Electrochimie des composes de surface:
nouveaux composes bidimensionales des molecules heterocycliques Name of institution: Laboratoire d'Electrochimie Interfaciale du
CNRS City: 92195 - Meudon/Bellevue, Francuska
Name of project
: Electrogeneration and properties of
tetraalkylammonium-antimony Name of institution: The Graduate School, University of Minnesota City: Minneapolis, SAD
Name of project
: 7405/EP Development of electrochemical
methodology for direct measurements of dissolved and dispersed organic
matter in coastal and estuarine waters Name of institution: International Atomic Energy Agency City: Beč, Austrija
Name of project
: Application of European Regional Seas
Ecological Model to the Adriatic Sea Name of institution: Plymouth Marine Laboratory City: Plymouth, UK
Name of project
: Management optimal se la mer cotiere contre la
pollution Name of institution: Observatoire Oceanologique City: Villefranche-sur-mer, France
Name of project
: Balance of nutrients in a coastal sea Name of institution: Centre d'Estudis Avancats de Blanes, Cami de
Santa Barbara s/n City: 17300 - Blanes, Espana
Name of project
: Organic electroreductions, synthesis and the
role of tetraalkylammonium ions Name of institution: National Science Foundation City: Minneapolis, SAD
Name of project
: Nacionalni monitoring zagađenja Jadrana
područja Krke i Kornata Name of institution: Ministarstvo graditeljstva i zaštite okoliša City: 10000 - Zagreb, Croatia
COOPERATION - INSTITUTIONS
Name of institution
: Državni hidrografski institut Type of institution: Institution whose primary activities ar City: 21000 - Split, Croatia
Name of institution
: Department of Chemistry, University of
Minnesota, Minneapolis Type of institution: Economical/Production City: Minneapolis, SAD
Name of institution
: Universite Pierre et Marie Curie,
Laboratoire d'Electrochimie Type of institution: Economical/Production Type of cooperation: Joint project City: 75230 - Pariz, Francuska
Name of institution
: Centre National de la Recherche
Sceintifique, Laboratoire d'Electrochimie des Interfaces Type of institution: University/Faculty City: 92195 - Meudon/Bellevue, Francuska
Name of institution
: Universite Pierre et Marie Curie,
Laboratoire de Physique et Chimie Marines Type of institution: Economical/Production Type of cooperation: Joint project City: 75230 - Pariz, Francuska
Name of institution
: Swiss Federal Institute for Aquatic
Sciences EAWAG/ETH Type of institution: State institute Type of cooperation: Joint project City: 8600 - Dubendorf/Zurich, Švicarska
Name of institution
: Ministarstvo graditeljstva i zaštite
okoliša Type of institution: State administration Type of cooperation: Joint project City: 10000 - Zagreb, Croatia
Name of institution
: Scientific Technological Research Council
(TUBITAK) Type of institution: State institute Type of cooperation: Systematic exchange of experts City: 41470 - Gebze, Turska
Name of institution
: UNEP-Mediterranean Action Plan Type of institution: International organization Type of cooperation: Joint project City: Atena, Grčka
Name of institution
: Nacionalni Park Krka Type of institution: Economical/Production Type of cooperation: Joint project City: 22000 - Šibenik, Croatia
OTHER ACHIEVEMENTS
Name
: Nagrada Rudjer Boskovic za znacajno znastveno otkrice Type of achievement: Other Authors: Dr. Vera Zutic i dr. Tarzan Legovic Other information about the project.