Type of research: basic Duration from: 01/01/91. to 12/15/95. Papers on project (total): 16
Papers on project quoted in Current Contents: 12
Institution name: Tehnološki fakultet, Split (11) Department/Institute: Department of Chemistry Laboratory for Analytical Chemistry Address: Teslina 10/V City: 21000 - Split, Croatia
Communication
Phone: 385 (0)21 341 633
Fax: 385 (0)21 341 624
E-mail: NJRADIC@MATEH.TEHST.HR
Summary: The potentiometric determination of mercury(II) and
thiourea (TU) in strong acid solution (pH 0 - 1) by using an
"all-solid-state" ion-selective electrode with (silver-sulfide 25%, AgI
25% and PTFE 50% m/m) - membrane is described. It was found that, by
direct potentiometry at pH 0, mercury(II) can be determined in the
presence of up to 1 mmol/L of iron(III). The linear response of the
electrode to TU has been discussed through the formation of Ag-TU complex
at the exposed surface of the membrane. Two kinetic methods have been
proposed by using fluoride ion-selective electrode (FISE). A
kinetic-potentiometric method is described for the determination of
Fe(III) based on monitoring of the formation of Fe(III)-monofluoride
complex in acid solution. A potentiometric method for the determination of
N-acetylcysteine (NAC) is based on its reduction action on Fe(III) in
acidic fluoride solution, pH 2. The method is described as an equilibrium
method and kinetic method. By using Cu(II)-ISE and a (Cu(II), EDTA and
La(III)) - filling as internal solution, the FISE with novel reversible
contact at the inner surface of the lanthanum fluoride membrane was
prepared. The aluminium-fluoride complex formation in water/acetonitrile
mixtures has been investigated using FISE. The overall formation constant
of the Al(III)-hexafluoride complex was determined. Potentiometric
determination of cysteine (Cys) in aqueous solution by using
iodide-selective electrode with (Ag2S + AgI) membrane is described. The
preparation of CuI + Ag2S and Cu2S(HgI4) + Ag2S membranes hydrophobised
by PTFE is described. The pressed membranes have been examined as
electrochemical sensors for copper(II) and iodide ions. A multi-purpose
solid-state iodide-selective electrode is constructed as a compact tubular
sensors. Application of the tubular electrode is exemplified by the
determination of cysteine and thiourea.
Research goals: The procedure of the preparation of solid-state
ion-selective electrodes with different membranes have been investigated
in the laboratory. Our aim was to develop a simple direct potentiometric
methods for determination of metal ions (mercury(II), copper(II),
iron(III), ...) or nonmetal species (thiourea, cysteine,
N-acetylcysteine, ...). Furthermore, our aim was to prepare CuISE with
pressed pellet which is contained an sparingly soluble Cu(I) salt instead
widely used CuS (or copper(I)-sulfide). The response of the electrode with
CuI + silver-sulfide and Cu(I)-tetraiodomercurate(II) + silver-sulfide
membrane hydrophobised by PTFE to copper(II) ion and iodide has been
studied. The behaviour of CuISEs with these membranes is under further
investigation. Combination of the simplicity of the kinetic method with
the advantages of fluorid ion-selective electrode (low detection limit,
high selectivity) produces an excellent analytical technique for
determination of metal ions that form complexes with fluoride. Our aim was
to develop two kinetic - potentiometric procedures, for the determination
iron(III) and N-acetylcysteine. Since the flow-injection analysis (FIA) is
rapidly developing into powerful analytical tool with many merits, our aim
is to develop a simple FIA system with flow-through potentiometric
sensors. A multi-purpose solid-state electrode with iodide selective
membrane will be constructed as a compact tubular sensor. The assembled
electrode will be applied as a sensor in FIA system for the determination
of thiourea and cysteine.
COOPERATION - INSTITUTIONS
Name of institution
: Department of Chemistry, University of
Cincinnati Type of institution: University/Faculty Type of cooperation: Joint publishing of scientific papers City: OH 45221 - Cincinnati, USA Other information about the project.