Type of research: basic Duration from: 01/01/91. to 12/15/95. Papers on project (total): 7
Papers on project quoted in Current Contents: 3
Institution name: Tehnološki fakultet, Split (11) Department/Institute: Laboratory of Physical Chemistry Address: 21000 Split, Teslina 10 City: 21000 - Split, Croatia
Communication
Phone: 385 (0)21 341633
Fax: 385 (0)21 341624
Summary: Association constant (KA), ion-pair radius (R), and
limiting molar conductivity (Lo) will be determined based on conductivity
measurements of NaBr electrolyte in tert. butanol-water and 2-butanol-water
mixtures in the temperature range 15-35řC, and by applying various
conductivity equations. From the values of KA obtained at different
temperatures the thermodynamic quantities will be established for
ion-association reaction Na+ and Br-. The influence of dielectric constant
and alcohol component on these quantities will be determined. From
electromotive force (EMF) measurements of the concentration cell with
transfer in tert. butanol-water mixtures in the temperature range 15-35řC
the stability constants will be established for various cadmium-chloride
complexes and also the thermodynamic quantities for the reactions forming
these complexes. From electromotive force measurements of chemical cells
without transfer with Cd-chloride in the same mixtures and in the same
temperature range the standard electromotive force of the cell will be
determined. These data will enable to obtain the thermodynamic quantities
which indicate the acid-base properties of the solvents and their
structure.
Research goals: The purpose of investigations is to gain an insight
into the ion-association reactions of 1-1 type electrolyte and the
reactions forming different complexes of 2-1 type electrolyte in mixed
solvents with lower dielectric constants containing water as one component.
The association reaction of HBr electrolyte was analyzed by taking into
account the conductivity measurements in water-butanol isomers mixtures,
and analogous investigations have been initiated with NaBr electrolyte. The
aim is to find out more about the suitability of using particular
theoretical conductivity equations for calculating the limiting molar
conductivity of electrolytes, the association constants and the ion
distance within the ion pairs; then, from the obtained parameter, to decide
on the mechanism of the ion transfer, the thermodynamics of the association
reaction and on the character of the ion pairs. Finally, the aim is to
learn about the influence on these parameters which is exerted by the
dielectric constant of the solvents and by the organic component. The
complexation reaction was studied with Cd-chloride electrolyte in
2-propanol-water and acetone-water mixtures, and measurements have been
started with tert. butanol-water mixtures. The aim is to determine the
stability constants for the cadmium complexes formed, and to estimate the
influence of the organic component on the obtained parameters. The results
obtained from investigations of the complexation reaction will then make it
possible, along with some additional measurements, to establish the
thermodynamic quantities for the reaction with transfer of Cd-chloride
electrolyte from the water into the mixed solvents under investigation, all
of which can assist in understanding their structure. Other information about the project.